Not in a very obvious way. The adjacency_list inherits from a metafunction (sort of) called adj_list_gen<...> type, which turns out to be either an adj_list_impl or a vec_adj_list_impl, with the latter corresponding to the vertex list selector == vecS. Both of these have members m_edges, and m_vertices, which correspond to the global edge and vertex sets. The types of these containers are (should be?) determined by the vecS, listS stuff, and (more importantly) appear to be public for both implementations.

I wrote that mainly for my own sake.

If you have a graph g, you might just try writing:

g.m_edges.reserve(n);